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SOLVED:Chiral catalysts can be designed to favor the formation of a single enantiomer in reactions where a new chiral center is formed. Recently, a novel type of chiral copper catalyst was developed that is "redox reconfigurable" in that the S enantiomer of the product predominates when the C u^I form of the catalyst is used, and the R enantiomer is the main product when the Cu ^11 form is used (see below). This is not a general phenomenon, and only works for a limited number of reactions. (a)
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